C:\Users\user1>runas /user:user2 "C:\Program Files (x86)\Google\Chrome\Application\Chrome.exe" Use runas command to start chrome with the credentials of another user. You can add this folder to the path by following the instructions from How to set path from command prompt How to open Chrome as a different user The installation path is "c:\Program Files (x86)\Google\Chrome\Application". However, you can make it work from CLI too by adding the chrome installation folder to the PATH environment variable. 'chrome' is not recognized as an internal or external command, Note that the run command is chrome whereas the CMD command is start chrome C:\>chrome Chrome can be opened from Run window by executing the command chrome.
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